AVCOLUX ETB is an optical brightening agent for polyester fibres and their blends to be applied by the thermosol and exhaust methods.AVCOLUX ETB-N is a tinted version of AVCOLUX ETB with more bluish shade.
SPECIFICATION:
Appearance |
Yellowish-white liquid (AVCOLUX ETB-N is greenish white). |
Chemical nature |
Optical brightener in aqueous dispersion. |
Ionicity |
Nonionic / anionic |
pH (1% sol.) |
Approx. 7.0 |
Solubility |
Dispersible in water |
Stability to hard water |
Good |
Stability:Peroxide bleaching bath, Sodium chlorite bath |
Very good, Limited |
Storage |
Sensitive to frost.When properly stored stable for at least 12 months. |
PROPERTIES & USES:
- AVCOLUX ETB produces excellent white effects of a neutral to bluish shade on
polyester fibres, when applied by the thermosol process at temperatures of 160-
2000C, or by the exhaust method, particularly under HT conditions at temperatures
of 110-130°C.
- Very good white effects are obtained even at fairly low temperatures due to the
high fixation capacity of AVCOLUX ETB.
- Excellent white effects are achieved on texturized polyester goods in the
thermosol process at temperatures as low as 1500C,taking into account the normal
dwell times. Generally speaking, however, such articles are thermosoled at
temperatures between 170 and 180°C.
- AVCOLUX ETB is very suitable for the brightening of the polyester component in
polyester/cellulosic blends. The brightener can be applied to the fibre before,
during or after peroxide bleaching.
- Polyester/cotton goods brightened with AVCOLUX ETB can be subsequently bleached
with chlorite without any problems, the product is fast to chlorite in this case.
It is not recommended to apply AVCOLUX ETB during chlorite bleaching.
- Very good effects are also achieved by applying AVCOLUX ETB together with resin
finishing agents by the shock curing method to goods ready for finishing.
Magnesium-chloride or a commercial shock curing catalyst are normally used as the
catalyst for the reactant resins used in this process. Zinc salts such as zinc
nitrate or zinc chloride may impair the white effect obtained with AVCOLUX ETB
when shock curing is the method used. A preliminary trial is therefore
recommended.
- AVCOLUX ETB produces attractive white effects on burn-out articles especially if
the burning-out process is followed by chlorite or hypochlorite bleaching.
- 8. The white effects can be further improved by applying the optical
brightener under HT conditions by the exhaust method in the presence of a
dispersing agent such as AVCONAL BM. When brightening is carried out at
temperatures near boiling, the addition of a suitable carrier produces somewhat
higher degrees of whiteness than just a dispersing agent.
- Over dosing of AVCOLUX ETB is causing yellowing of the optical brightening effect.
REMARK:
In all the guiding receips in the Application part apply AVCOLUX ETB or
AVCOLUX ETB-N according to the required white effect.
APPLICATION:
-
Thermosol process:
-
Polyester (100%) – apply AVCOLUX ETB 2 – 6 g/l
-
Polyester/cotton (65/35)- apply AVCOLUX ETB 2 – 4 g/l
Thermosol for 30-20 seconds at 170-195°C, or for 50-30 seconds at 150-180°C in the case of texturized polyester.
-
Polyester (100%) HT process
Use the following procedure:
AVCOLUX ETB -0.2 – 0.5%
AVCONAL BM -1.0 g/l
Adjust pH to 5-5.5 with acetic acid.
Liquor ratio 5:1 – 15:1
start at 400C, heat up to 130°C.
Hold for 30 min. at 1300C , cool down and drop bath.
-
Polyester (100%) atmospheric machines
Use the following procedure:
AVCOLUX ETB – 0.2 – 0.5%
AVCOCAR CT -2.0 – 4 g/l
AVCONAL BM -1.0 g/l
Adjust pH to 5-5.5 with acetic acid.
Liquor ratio 5:1 – 15:1
temperature: 98-105°C, time: 60 min.
-
One step bleaching and brightening of polyester/cotton
Use the following procedure:
AVCOLUX CBA – 0.2 – 0.5%
AVCOLUX ETB – 0.1 – 0.4%
H2O2(35%) – 6 cc/l
BLANKINOL AWS – 3 g/l
AVCONAL BM – 1 g/l
AVCOCAR CT – 1.0 – 3 .0 g/l
Liquor ratio 10:1 – 15:1.
Temperature: 95-98°C
Time – 60 min.
Dry and heat-set
FASTNESS PROPERTIES ON FIBRES:
-
Light fastness (DIN 54004) – 6
-
Wash fastness (60°C) (DIN 54010) – 5
-
Fastness to hypochlorite bleaching (2 g/l active chlorine) (DIN 54035) – 5
-
Fastness to dry heat setting and pleating (180°C) (DIN 54060) – 5
-
Fastness to perspiration, alkaline (DIN 54020) – 5
-
Fastness to perspiration, acid (DIN 54020) – 5
-
Fastness to acid (DIN 54028) – 5
-
Fastness to nitrogen oxides (DIN 54025) – 5
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